

It may be the basic ubuntu telemetry (relatively non-invasive, but still a concern for the privacy-minded) sent by this tool unless you opted out at install:
https://github.com/ubuntu/ubuntu-report
from that page:
So it would not surprise me if it was scheduled to send, failed, and then re-triggered upon activation of a new network connection (the VPN).
Edit: Or even more likely, it is a connection from networkmanager to connectivity-check.ubuntu.com
https://ubuntu.com/core/docs/networkmanager/snap-configuration/connectivity-check
https://librewolf.net/docs/faq/#can-i-use-firefox-sync-with-librewolf-is-it-safe-to-do-so